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| U | CD Leonesa | - | Real Madrid | 1:7 (0:2) | ||
| R | Real Madrid | - | CD Leonesa | 6:1 (3:1) | ||
| U: 26.10.2016 21:00 | R: 30.11.2016 19:00 | Winnaars: Real Madrid | ||||
| U | CD Leganés | - | Valencia CF | 1:3 (0:2) | ||
| R | Valencia CF | - | CD Leganés | 2:1 (1:0) | ||
| U: 29.11.2016 20:00 | R: 21.12.2016 21:00 | Winnaars: Valencia CF | ||||
| U | AD Alcorcón | - | Espanyol | 1:1 (0:0) | ||
| R | Espanyol | - | AD Alcorcón | 3:4 (0:1, 1:1, 1:1) d.p. | ||
| U: 29.11.2016 21:00 | R: 22.12.2016 21:00 | Winnaars: AD Alcorcón | ||||
| U | Sporting Gijón | - | SD Eibar | 1:2 (0:1) | ||
| R | SD Eibar | - | Sporting Gijón | 3:1 (2:0) | ||
| U: 29.11.2016 21:00 | R: 21.12.2016 19:00 | Winnaars: SD Eibar | ||||
| U | Real Betis | - | Deportivo La Coruña | 1:0 (1:0) | ||
| R | Deportivo La Coruña | - | Real Betis | 3:1 (1:0) | ||
| U: 29.11.2016 22:00 | R: 21.12.2016 21:00 | Winnaars: Deportivo La Coruña | ||||
| U | CD Toledo | - | Villarreal CF | 0:3 (0:2) | ||
| R | Villarreal CF | - | CD Toledo | 1:1 (0:0) | ||
| U: 30.11.2016 19:00 | R: 20.12.2016 19:00 | Winnaars: Villarreal CF | ||||
| U | SD Formentera | - | Sevilla FC | 1:5 (1:4) | ||
| R | Sevilla FC | - | SD Formentera | 9:1 (6:0) | ||
| U: 30.11.2016 19:00 | R: 21.12.2016 19:00 | Winnaars: Sevilla FC | ||||
| U | CD Guijuelo | - | Atlético Madrid | 0:6 (0:2) | ||
| R | Atlético Madrid | - | CD Guijuelo | 4:1 (4:0) | ||
| U: 30.11.2016 21:00 | R: 20.12.2016 21:00 | Winnaars: Atlético Madrid | ||||
| U | UCAM Murcia CF | - | Celta de Vigo | 0:1 (0:1) | ||
| R | Celta de Vigo | - | UCAM Murcia CF | 1:0 (1:0) | ||
| U: 30.11.2016 21:00 | R: 22.12.2016 20:00 | Winnaars: Celta de Vigo | ||||
| U | Córdoba CF | - | Málaga CF | 2:0 (0:0) | ||
| R | Málaga CF | - | Córdoba CF | 3:4 (2:2) | ||
| U: 30.11.2016 21:00 | R: 20.12.2016 21:00 | Winnaars: Córdoba CF | ||||
| U | Granada CF | - | CA Osasuna | 1:0 (0:0) | ||
| R | CA Osasuna | - | Granada CF | 2:0 (1:0) | ||
| U: 30.11.2016 21:00 | R: 21.12.2016 21:00 | Winnaars: CA Osasuna | ||||
| U | Hércules CF | - | FC Barcelona | 1:1 (0:0) | ||
| R | FC Barcelona | - | Hércules CF | 7:0 (2:0) | ||
| U: 30.11.2016 22:00 | R: 21.12.2016 22:00 | Winnaars: FC Barcelona | ||||
| U | Real Valladolid | - | Real Sociedad | 1:3 (1:1) | ||
| R | Real Sociedad | - | Real Valladolid | 1:1 (1:1) | ||
| U: 01.12.2016 20:00 | R: 20.12.2016 20:00 | Winnaars: Real Sociedad | ||||
| U | SD Huesca | - | UD Las Palmas | 2:2 (0:1) | ||
| R | UD Las Palmas | - | SD Huesca | 2:1 (1:0) | ||
| U: 01.12.2016 21:00 | R: 20.12.2016 21:00 | Winnaars: UD Las Palmas | ||||
| U | Gimnàstic de Tarragona | - | Deportivo Alavés | 0:3 (0:1) | ||
| R | Deportivo Alavés | - | Gimnàstic de Tarragona | 3:0 (3:0) | ||
| U: 01.12.2016 21:00 | R: 22.12.2016 20:00 | Winnaars: Deportivo Alavés | ||||
| U | Racing Santander | - | Athletic Bilbao | 1:2 (1:2) | ||
| R | Athletic Bilbao | - | Racing Santander | 3:0 (1:0) | ||
| U: 01.12.2016 22:00 | R: 22.12.2016 21:00 | Winnaars: Athletic Bilbao | ||||
