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| U | Sporting CP | - | Manchester City | 0:5 (0:4) | ||
| R | Manchester City | - | Sporting CP | 0:0 (0:0) | ||
| U: 15.02.2022 21:00 | R: 09.03.2022 21:00 | Winnaars: Manchester City | ||||
| U | Paris Saint-Germain | - | Real Madrid | 1:0 (0:0) | ||
| R | Real Madrid | - | Paris Saint-Germain | 3:1 (0:1) | ||
| U: 15.02.2022 21:00 | R: 09.03.2022 21:00 | Winnaars: Real Madrid | ||||
| U | RB Salzburg | - | Bayern München | 1:1 (1:0) | ||
| R | Bayern München | - | RB Salzburg | 7:1 (4:0) | ||
| U: 16.02.2022 21:00 | R: 08.03.2022 21:00 | Winnaars: Bayern München | ||||
| U | Inter | - | Liverpool FC | 0:2 (0:0) | ||
| R | Liverpool FC | - | Inter | 0:1 (0:0) | ||
| U: 16.02.2022 21:00 | R: 08.03.2022 21:00 | Winnaars: Liverpool FC | ||||
| U | Chelsea FC | - | Lille OSC | 2:0 (1:0) | ||
| R | Lille OSC | - | Chelsea FC | 1:2 (1:1) | ||
| U: 22.02.2022 21:00 | R: 16.03.2022 21:00 | Winnaars: Chelsea FC | ||||
| U | Villarreal CF | - | Juventus | 1:1 (0:1) | ||
| R | Juventus | - | Villarreal CF | 0:3 (0:0) | ||
| U: 22.02.2022 21:00 | R: 16.03.2022 21:00 | Winnaars: Villarreal CF | ||||
| U | SL Benfica | - | AFC Ajax | 2:2 (1:2) | ||
| R | AFC Ajax | - | SL Benfica | 0:1 (0:0) | ||
| U: 23.02.2022 21:00 | R: 15.03.2022 21:00 | Winnaars: SL Benfica | ||||
| U | Atlético Madrid | - | Manchester United | 1:1 (1:0) | ||
| R | Manchester United | - | Atlético Madrid | 0:1 (0:1) | ||
| U: 23.02.2022 21:00 | R: 15.03.2022 21:00 | Winnaars: Atlético Madrid | ||||
