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| U | AC Milan | - | Tottenham Hotspur | 1:0 (1:0) | ||
| R | Tottenham Hotspur | - | AC Milan | 0:0 (0:0) | ||
| U: 14.02.2023 21:00 | R: 08.03.2023 21:10 | Winnaars: AC Milan | ||||
| U | Paris Saint-Germain | - | Bayern München | 0:1 (0:0) | ||
| R | Bayern München | - | Paris Saint-Germain | 2:0 (0:0) | ||
| U: 14.02.2023 21:00 | R: 08.03.2023 21:00 | Winnaars: Bayern München | ||||
| U | Club Brugge KV | - | SL Benfica | 0:2 (0:0) | ||
| R | SL Benfica | - | Club Brugge KV | 5:1 (2:0) | ||
| U: 15.02.2023 21:00 | R: 07.03.2023 21:00 | Winnaars: SL Benfica | ||||
| U | Borussia Dortmund | - | Chelsea FC | 1:0 (0:0) | ||
| R | Chelsea FC | - | Borussia Dortmund | 2:0 (1:0) | ||
| U: 15.02.2023 21:00 | R: 07.03.2023 21:10 | Winnaars: Chelsea FC | ||||
| U | Liverpool FC | - | Real Madrid | 2:5 (2:2) | ||
| R | Real Madrid | - | Liverpool FC | 1:0 (0:0) | ||
| U: 21.02.2023 21:00 | R: 15.03.2023 21:00 | Winnaars: Real Madrid | ||||
| U | Eintracht Frankfurt | - | SSC Napoli | 0:2 (0:1) | ||
| R | SSC Napoli | - | Eintracht Frankfurt | 3:0 (1:0) | ||
| U: 21.02.2023 21:00 | R: 15.03.2023 21:00 | Winnaars: SSC Napoli | ||||
| U | RB Leipzig | - | Manchester City | 1:1 (0:1) | ||
| R | Manchester City | - | RB Leipzig | 7:0 (3:0) | ||
| U: 22.02.2023 21:00 | R: 14.03.2023 21:00 | Winnaars: Manchester City | ||||
| U | Inter | - | FC Porto | 1:0 (0:0) | ||
| R | FC Porto | - | Inter | 0:0 (0:0) | ||
| U: 22.02.2023 21:00 | R: 14.03.2023 21:00 | Winnaars: Inter | ||||
