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| 02.04.2022 | 12:00 | Athletic Bilbao | - | Valencia CF | 2:2 (1:1) | |
| 12:00 | FC Barcelona | - | Villarreal CF | 6:1 (0:1) | ||
| 12:30 | Real Sociedad | - | Madrid CFF | 0:1 (0:1) | ||
| 17:00 | Real Betis | - | Atlético Madrid | 1:1 (1:0) | ||
| 03.04.2022 | 11:00 | Levante UD | - | Sevilla FC | 3:0 (2:0) | |
| 11:30 | SD Eibar | - | CD Alavés | 2:0 (1:0) | ||
| 12:00 | Sporting de Huelva | - | Real Madrid | 3:1 (3:1) | ||
| 12:00 | Rayo Vallecano | - | UDG Tenerife Sur | 1:2 (1:1) |
| » Stand | Thuis | uit | Heenronde | Returnronde |
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
FC Barcelona | 26 | 26 | 0 | 0 | 144:8 | 136 | 78 |
| 2 |
|
Real Sociedad | 26 | 18 | 2 | 6 | 54:35 | 19 | 56 |
| 3 |
|
Atlético Madrid | 26 | 14 | 8 | 4 | 59:25 | 34 | 50 |
| 4 |
|
Real Madrid | 26 | 16 | 2 | 8 | 38:31 | 7 | 50 |
| 5 |
|
UDG Tenerife Sur | 26 | 15 | 5 | 6 | 36:35 | 1 | 50 |
| 6 |
|
Levante UD | 26 | 12 | 5 | 9 | 41:29 | 12 | 41 |
| 7 |
|
Athletic Bilbao | 26 | 12 | 5 | 9 | 39:38 | 1 | 41 |
| 8 |
|
Sevilla FC | 26 | 8 | 8 | 10 | 28:43 | -15 | 32 |
| 9 |
|
CD Alavés | 26 | 8 | 6 | 12 | 27:51 | -24 | 30 |
| 10 |
|
Real Betis | 26 | 7 | 8 | 11 | 28:45 | -17 | 29 |
| 11 |
|
Madrid CFF | 26 | 8 | 2 | 16 | 39:56 | -17 | 26 |
| 12 |
|
Valencia CF | 26 | 7 | 4 | 15 | 26:49 | -23 | 25 |
| 13 |
|
Sporting de Huelva | 26 | 4 | 12 | 10 | 22:39 | -17 | 24 |
| 14 |
|
Villarreal CF | 26 | 7 | 3 | 16 | 25:60 | -35 | 24 |
| 15 |
|
SD Eibar | 26 | 6 | 1 | 19 | 26:55 | -29 | 19 |
| 16 |
|
Rayo Vallecano | 26 | 2 | 5 | 19 | 20:53 | -33 | 11 |
| Champions League | |
| Champions League Kwali. | |
| Degradatie |
