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| 20.03.1966 | Racing Santander | - | UE Lleida | 0:0 | ||
| CA Osasuna | - | CE Europa | 3:0 | |||
| Real Oviedo | - | Burgos CF | 0:0 | |||
| Celta de Vigo | - | Sporting Gijón | 2:1 | |||
| Barakaldo CF | - | SD Indautxu | 1:4 | |||
| Deportivo La Coruña | - | UP Langreo | 4:0 | |||
| CF Badalona | - | CD Condal | 2:0 | |||
| CE L'Hospitalet | - | Real Sociedad | 1:2 | |||
| Real Valladolid | - | CD Tenerife | 5:1 | |||
| Levante UD | - | Real Murcia | 6:0 | |||
| Recreativo Huelva | - | Hércules CF | 1:1 | |||
| Algeciras CF | - | UD Melilla | 3:1 | |||
| CF Calvo Sotelo | - | CD Badajoz | 3:1 | |||
| Granada CF | - | Cádiz CF | 2:0 | |||
| CA Ceuta | - | Rayo Vallecano | 1:1 | |||
| CD Constància | - | CD Mestalla | 2:1 |
| » Stand | Thuis | uit | Heenronde | Returnronde |
| 1 | |||||||||
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Deportivo La Coruña | 28 | 17 | 6 | 5 | 46:16 | 30 | 40:16 |
| 2 |
|
Celta de Vigo | 28 | 16 | 5 | 7 | 52:26 | 26 | 37:19 |
| 3 |
|
Sporting Gijón | 28 | 14 | 6 | 8 | 64:44 | 20 | 34:22 |
| 4 |
|
Real Oviedo | 28 | 13 | 8 | 7 | 36:18 | 18 | 34:22 |
| 5 |
|
CA Osasuna | 28 | 13 | 4 | 11 | 38:38 | 0 | 30:26 |
| 6 |
|
Burgos CF | 28 | 12 | 5 | 11 | 37:38 | -1 | 29:27 |
| 7 |
|
SD Indautxu | 28 | 13 | 3 | 12 | 45:46 | -1 | 29:27 |
| 8 |
|
CD Condal | 28 | 13 | 3 | 12 | 52:44 | 8 | 29:27 |
| 9 |
|
Real Sociedad | 28 | 12 | 5 | 11 | 48:46 | 2 | 29:27 |
| 10 |
|
CF Badalona | 28 | 12 | 4 | 12 | 28:37 | -9 | 28:28 |
| 11 |
|
UE Lleida | 28 | 9 | 9 | 10 | 35:31 | 4 | 27:29 |
| 12 |
|
Racing Santander | 28 | 9 | 9 | 10 | 35:39 | -4 | 27:29 |
| 13 |
|
UP Langreo | 28 | 10 | 3 | 15 | 37:55 | -18 | 23:33 |
| 14 |
|
CE Europa | 28 | 8 | 5 | 15 | 29:46 | -17 | 21:35 |
| 15 |
|
CE L'Hospitalet | 28 | 9 | 0 | 19 | 35:59 | -24 | 18:38 |
| 16 |
|
Barakaldo CF | 28 | 5 | 3 | 20 | 24:58 | -34 | 13:43 |
| 2 | |||||||||
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Hércules CF | 28 | 15 | 7 | 6 | 42:23 | 19 | 37:19 |
| 2 |
|
Real Valladolid | 28 | 13 | 8 | 7 | 46:28 | 18 | 34:22 |
| 3 |
|
CD Mestalla | 28 | 10 | 13 | 5 | 44:36 | 8 | 33:23 |
| 4 |
|
Granada CF | 28 | 14 | 5 | 9 | 36:29 | 7 | 33:23 |
| 5 |
|
Algeciras CF | 28 | 13 | 6 | 9 | 36:27 | 9 | 32:24 |
| 6 |
|
Levante UD | 28 | 11 | 8 | 9 | 40:22 | 18 | 30:26 |
| 7 |
|
CF Calvo Sotelo | 28 | 12 | 6 | 10 | 32:34 | -2 | 30:26 |
| 8 |
|
CD Tenerife | 28 | 12 | 6 | 10 | 39:30 | 9 | 30:26 |
| 9 |
|
Rayo Vallecano | 28 | 11 | 7 | 10 | 33:24 | 9 | 29:27 |
| 10 |
|
Real Murcia | 28 | 11 | 5 | 12 | 26:32 | -6 | 27:29 |
| 11 |
|
Recreativo Huelva | 28 | 10 | 7 | 11 | 26:28 | -2 | 27:29 |
| 12 |
|
Cádiz CF | 28 | 9 | 7 | 12 | 24:27 | -3 | 25:31 |
| 13 |
|
CD Constància | 28 | 9 | 6 | 13 | 31:45 | -14 | 24:32 |
| 14 |
|
CA Ceuta | 28 | 10 | 3 | 15 | 31:42 | -11 | 23:33 |
| 15 |
|
UD Melilla | 28 | 6 | 6 | 16 | 23:49 | -26 | 18:38 |
| 16 |
|
CD Badajoz | 28 | 4 | 8 | 16 | 21:54 | -33 | 16:40 |
