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| U | Anzhi Makhachkala | - | KRC Genk | 0:0 (0:0) | ||
| R | KRC Genk | - | Anzhi Makhachkala | 0:2 (0:0) | ||
| U: 20.02.2014 18:00 | R: 27.02.2014 21:05 | Winnaars: Anzhi Makhachkala | ||||
| U | Dnipro Dnipropetrovsk | - | Tottenham Hotspur | 1:0 (0:0) | ||
| R | Tottenham Hotspur | - | Dnipro Dnipropetrovsk | 3:1 (0:0) | ||
| U: 20.02.2014 19:00 | R: 27.02.2014 21:05 | Winnaars: Tottenham Hotspur | ||||
| U | Juventus | - | Trabzonspor | 2:0 (1:0) | ||
| R | Trabzonspor | - | Juventus | 0:2 (0:2) | ||
| U: 20.02.2014 19:00 | R: 27.02.2014 21:05 | Winnaars: Juventus | ||||
| U | Chernomorets Odessa | - | Olympique Lyon | 0:0 (0:0) | ||
| R | Olympique Lyon | - | Chernomorets Odessa | 1:0 (0:0) | ||
| U: 20.02.2014 19:00 | R: 27.02.2014 21:05 | Winnaars: Olympique Lyon | ||||
| U | Esbjerg fB | - | ACF Fiorentina | 1:3 (1:3) | ||
| R | ACF Fiorentina | - | Esbjerg fB | 1:1 (0:0) | ||
| U: 20.02.2014 19:00 | R: 27.02.2014 21:05 | Winnaars: ACF Fiorentina | ||||
| U | Dinamo Kiev | - | Valencia CF | 0:2 (0:0) | ||
| R | Valencia CF | - | Dinamo Kiev | 0:0 (0:0) | ||
| U: 20.02.2014 19:00 | R: 27.02.2014 21:05 | Winnaars: Valencia CF | ||||
| U | PAOK Saloniki | - | SL Benfica | 0:1 (0:0) | ||
| R | SL Benfica | - | PAOK Saloniki | 3:0 (0:0) | ||
| U: 20.02.2014 19:00 | R: 27.02.2014 21:05 | Winnaars: SL Benfica | ||||
| U | Slovan Liberec | - | AZ Alkmaar | 0:1 (0:0) | ||
| R | AZ Alkmaar | - | Slovan Liberec | 1:1 (1:0) | ||
| U: 20.02.2014 19:00 | R: 27.02.2014 21:05 | Winnaars: AZ Alkmaar | ||||
| U | Real Betis | - | Rubin Kazan | 1:1 (1:0) | ||
| R | Rubin Kazan | - | Real Betis | 0:2 (0:1) | ||
| U: 20.02.2014 21:05 | R: 27.02.2014 18:00 | Winnaars: Real Betis | ||||
| U | Swansea City | - | SSC Napoli | 0:0 (0:0) | ||
| R | SSC Napoli | - | Swansea City | 3:1 (1:1) | ||
| U: 20.02.2014 21:05 | R: 27.02.2014 19:00 | Winnaars: SSC Napoli | ||||
| U | NK Maribor | - | Sevilla FC | 2:2 (1:0) | ||
| R | Sevilla FC | - | NK Maribor | 2:1 (1:0) | ||
| U: 20.02.2014 21:05 | R: 27.02.2014 19:00 | Winnaars: Sevilla FC | ||||
| U | Viktoria Plzeň | - | Shakhtar Donetsk | 1:1 (0:0) | ||
| R | Shakhtar Donetsk | - | Viktoria Plzeň | 1:2 (0:2) | ||
| U: 20.02.2014 21:05 | R: 27.02.2014 19:00 | Winnaars: Viktoria Plzeň | ||||
| U | Lazio Roma | - | PFC Ludogorets Razgrad | 0:1 (0:1) | ||
| R | PFC Ludogorets Razgrad | - | Lazio Roma | 3:3 (0:1) | ||
| U: 20.02.2014 21:05 | R: 27.02.2014 19:00 | Winnaars: PFC Ludogorets Razgrad | ||||
| U | AFC Ajax | - | RB Salzburg | 0:3 (0:3) | ||
| R | RB Salzburg | - | AFC Ajax | 3:1 (0:0) | ||
| U: 20.02.2014 21:05 | R: 27.02.2014 19:00 | Winnaars: RB Salzburg | ||||
| U | Maccabi Tel Aviv | - | FC Basel | 0:0 (0:0) | ||
| R | FC Basel | - | Maccabi Tel Aviv | 3:0 (1:0) | ||
| U: 20.02.2014 21:05 | R: 27.02.2014 19:00 | Winnaars: FC Basel | ||||
| U | FC Porto | - | Eintracht Frankfurt | 2:2 (1:0) | ||
| R | Eintracht Frankfurt | - | FC Porto | 3:3 (1:0) | ||
| U: 20.02.2014 21:05 | R: 27.02.2014 19:00 | Winnaars: FC Porto | ||||
