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| U | Sporting CP | - | İstanbul Başakşehir | 3:1 (2:0) | ||
| R | İstanbul Başakşehir | - | Sporting CP | 4:1 (2:0, 3:1) n.v. | ||
| U: 20.02.2020 18:55 | R: 27.02.2020 18:55 | Winnaars: İstanbul Başakşehir | ||||
| U | Getafe CF | - | AFC Ajax | 2:0 (1:0) | ||
| R | AFC Ajax | - | Getafe CF | 2:1 (1:1) | ||
| U: 20.02.2020 18:55 | R: 27.02.2020 21:00 | Winnaars: Getafe CF | ||||
| U | FC Kopenhagen | - | Celtic FC | 1:1 (0:1) | ||
| R | Celtic FC | - | FC Kopenhagen | 1:3 (0:0) | ||
| U: 20.02.2020 18:55 | R: 27.02.2020 21:00 | Winnaars: FC Kopenhagen | ||||
| U | CFR Cluj | - | Sevilla FC | 1:1 (0:0) | ||
| R | Sevilla FC | - | CFR Cluj | 0:0 (0:0) | ||
| U: 20.02.2020 18:55 | R: 27.02.2020 21:00 | Winnaars: Sevilla FC | ||||
| U | Club Brugge KV | - | Manchester United | 1:1 (1:1) | ||
| R | Manchester United | - | Club Brugge KV | 5:0 (3:0) | ||
| U: 20.02.2020 18:55 | R: 27.02.2020 21:00 | Winnaars: Manchester United | ||||
| U | PFC Ludogorets Razgrad | - | Inter | 0:2 (0:0) | ||
| R | Inter | - | PFC Ludogorets Razgrad | 2:1 (2:1) | ||
| U: 20.02.2020 18:55 | R: 27.02.2020 21:00 | Winnaars: Inter | ||||
| U | Eintracht Frankfurt | - | RB Salzburg | 4:1 (2:0) | ||
| R | RB Salzburg | - | Eintracht Frankfurt | 2:2 (1:1) | ||
| U: 20.02.2020 18:55 | R: 28.02.2020 18:00 | Winnaars: Eintracht Frankfurt | ||||
| U | Shakhtar Donetsk | - | SL Benfica | 2:1 (0:0) | ||
| R | SL Benfica | - | Shakhtar Donetsk | 3:3 (2:1) | ||
| U: 20.02.2020 18:55 | R: 27.02.2020 21:00 | Winnaars: Shakhtar Donetsk | ||||
| U | Wolverhampton Wanderers | - | Espanyol | 4:0 (1:0) | ||
| R | Espanyol | - | Wolverhampton Wanderers | 3:2 (1:1) | ||
| U: 20.02.2020 21:00 | R: 27.02.2020 18:55 | Winnaars: Wolverhampton Wanderers | ||||
| U | Bayer Leverkusen | - | FC Porto | 2:1 (1:0) | ||
| R | FC Porto | - | Bayer Leverkusen | 1:3 (0:1) | ||
| U: 20.02.2020 21:00 | R: 27.02.2020 18:55 | Winnaars: Bayer Leverkusen | ||||
| U | APOEL Nicosia | - | FC Basel | 0:3 (0:1) | ||
| R | FC Basel | - | APOEL Nicosia | 1:0 (1:0) | ||
| U: 20.02.2020 21:00 | R: 27.02.2020 18:55 | Winnaars: FC Basel | ||||
| U | Olympiakos | - | Arsenal FC | 0:1 (0:0) | ||
| R | Arsenal FC | - | Olympiakos | 1:2 (0:0, 0:1) n.v. | ||
| U: 20.02.2020 21:00 | R: 27.02.2020 21:00 | Winnaars: Olympiakos | ||||
| U | AZ Alkmaar | - | LASK | 1:1 (0:1) | ||
| R | LASK | - | AZ Alkmaar | 2:0 (1:0) | ||
| U: 20.02.2020 21:00 | R: 27.02.2020 18:55 | Winnaars: LASK | ||||
| U | VfL Wolfsburg | - | Malmö FF | 2:1 (0:0) | ||
| R | Malmö FF | - | VfL Wolfsburg | 0:3 (0:1) | ||
| U: 20.02.2020 21:00 | R: 27.02.2020 18:55 | Winnaars: VfL Wolfsburg | ||||
| U | AS Roma | - | KAA Gent | 1:0 (1:0) | ||
| R | KAA Gent | - | AS Roma | 1:1 (1:1) | ||
| U: 20.02.2020 21:00 | R: 27.02.2020 18:55 | Winnaars: AS Roma | ||||
| U | Rangers FC | - | Sporting Braga | 3:2 (0:1) | ||
| R | Sporting Braga | - | Rangers FC | 0:1 (0:0) | ||
| U: 20.02.2020 21:00 | R: 26.02.2020 18:00 | Winnaars: Rangers FC | ||||
