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| U | AFC Ajax | - | BSC Young Boys | 3:0 (0:0) | ||
| R | BSC Young Boys | - | AFC Ajax | 0:2 (0:1) | ||
| U: 11.03.2021 18:55 | R: 18.03.2021 21:00 | Winnaars: AFC Ajax | ||||
| U | Dinamo Kiev | - | Villarreal CF | 0:2 (0:1) | ||
| R | Villarreal CF | - | Dinamo Kiev | 2:0 (2:0) | ||
| U: 11.03.2021 18:55 | R: 18.03.2021 21:00 | Winnaars: Villarreal CF | ||||
| U | Manchester United | - | AC Milan | 1:1 (0:0) | ||
| R | AC Milan | - | Manchester United | 0:1 (0:0) | ||
| U: 11.03.2021 18:55 | R: 18.03.2021 21:00 | Winnaars: Manchester United | ||||
| U | Slavia Praag | - | Rangers FC | 1:1 (1:1) | ||
| R | Rangers FC | - | Slavia Praag | 0:2 (0:1) | ||
| U: 11.03.2021 18:55 | R: 18.03.2021 21:00 | Winnaars: Slavia Praag | ||||
| U | AS Roma | - | Shakhtar Donetsk | 3:0 (1:0) | ||
| R | Shakhtar Donetsk | - | AS Roma | 1:2 (0:0) | ||
| U: 11.03.2021 21:00 | R: 18.03.2021 18:55 | Winnaars: AS Roma | ||||
| U | Olympiakos | - | Arsenal FC | 1:3 (0:1) | ||
| R | Arsenal FC | - | Olympiakos | 0:1 (0:0) | ||
| U: 11.03.2021 21:00 | R: 18.03.2021 18:55 | Winnaars: Arsenal FC | ||||
| U | Tottenham Hotspur | - | Dinamo Zagreb | 2:0 (1:0) | ||
| R | Dinamo Zagreb | - | Tottenham Hotspur | 3:0 (0:0, 2:0, 3:0) n.v. | ||
| U: 11.03.2021 21:00 | R: 18.03.2021 18:55 | Winnaars: Dinamo Zagreb | ||||
| U | Granada CF | - | Molde FK | 2:0 (1:0) | ||
| R | Molde FK | - | Granada CF | 2:1 (1:0) | ||
| U: 11.03.2021 21:00 | R: 18.03.2021 18:55 | Winnaars: Granada CF | ||||
