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| U | FC Barcelona | - | Manchester United | 2:2 (0:0) | ||
| R | Manchester United | - | FC Barcelona | 2:1 (0:1) | ||
| U: 16.02.2023 18:45 | R: 23.02.2023 21:00 | Winnaars: Manchester United | ||||
| U | Shakhtar Donetsk | - | Stade Rennes | 2:1 (2:0) | ||
| R | Stade Rennes | - | Shakhtar Donetsk | 4:5 (0:0, 1:0, 2:1) d.p. | ||
| U: 16.02.2023 18:45 | R: 23.02.2023 21:00 | Winnaars: Shakhtar Donetsk | ||||
| U | AFC Ajax | - | 1. FC Union Berlin | 0:0 (0:0) | ||
| R | 1. FC Union Berlin | - | AFC Ajax | 3:1 (2:0) | ||
| U: 16.02.2023 18:45 | R: 23.02.2023 21:00 | Winnaars: 1. FC Union Berlin | ||||
| U | RB Salzburg | - | AS Roma | 1:0 (0:0) | ||
| R | AS Roma | - | RB Salzburg | 2:0 (2:0) | ||
| U: 16.02.2023 18:45 | R: 23.02.2023 21:00 | Winnaars: AS Roma | ||||
| U | Juventus | - | FC Nantes | 1:1 (1:0) | ||
| R | FC Nantes | - | Juventus | 0:3 (0:2) | ||
| U: 16.02.2023 21:00 | R: 23.02.2023 18:45 | Winnaars: Juventus | ||||
| U | Sporting CP | - | FC Midtjylland | 1:1 (0:0) | ||
| R | FC Midtjylland | - | Sporting CP | 0:4 (0:1) | ||
| U: 16.02.2023 21:00 | R: 23.02.2023 18:45 | Winnaars: Sporting CP | ||||
| U | Bayer Leverkusen | - | AS Monaco | 2:3 (0:1) | ||
| R | AS Monaco | - | Bayer Leverkusen | 3:5 (1:2, 2:3, 2:3) d.p. | ||
| U: 16.02.2023 21:00 | R: 23.02.2023 18:45 | Winnaars: Bayer Leverkusen | ||||
| U | Sevilla FC | - | PSV | 3:0 (1:0) | ||
| R | PSV | - | Sevilla FC | 2:0 (0:0) | ||
| U: 16.02.2023 21:00 | R: 23.02.2023 18:45 | Winnaars: Sevilla FC | ||||
