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| 09.10.1966 | Racing Santander | - | Racing Ferrol | 1:0 | ||
| Real Valladolid | - | SD Indautxu | 3:1 | |||
| Rayo Vallecano | - | Gimnástica Torrelavega | 2:1 | |||
| CA Osasuna | - | Burgos CF | 1:1 | |||
| CD Tenerife | - | CD Logroñés | 3:1 | |||
| Real Oviedo | - | Real Sociedad | 2:2 | |||
| Celta de Vigo | - | UP Langreo | 2:1 | |||
| CF Calvo Sotelo | - | Sporting Gijón | 1:0 | |||
| CD Castellón | - | CE Europa | 2:0 | |||
| RCD Mallorca | - | Algeciras CF | 3:1 | |||
| Real Murcia | - | UE Lleida | 3:0 | |||
| Recreativo Huelva | - | Levante UD | 0:1 | |||
| CD Mestalla | - | CD Constància | 3:2 | |||
| CF Badalona | - | Cádiz CF | 1:1 | |||
| CA Ceuta | - | Real Betis | 1:0 | |||
| CD Condal | - | CD Málaga | 1:2 |
| » Stand | Thuis | uit | Heenronde | Returnronde |
| 1 | |||||||||
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Rayo Vallecano | 5 | 4 | 0 | 1 | 13:2 | 11 | 8:2 |
| 2 |
|
Racing Santander | 5 | 4 | 0 | 1 | 10:3 | 7 | 8:2 |
| 3 |
|
Sporting Gijón | 5 | 3 | 1 | 1 | 8:2 | 6 | 7:3 |
| 4 |
|
CF Calvo Sotelo | 5 | 3 | 1 | 1 | 7:2 | 5 | 7:3 |
| 5 |
|
Racing Ferrol | 5 | 3 | 0 | 2 | 11:4 | 7 | 6:4 |
| 6 |
|
Celta de Vigo | 5 | 3 | 0 | 2 | 8:6 | 2 | 6:4 |
| 7 |
|
Real Sociedad | 5 | 2 | 1 | 2 | 6:9 | -3 | 5:5 |
| 8 |
|
Real Oviedo | 5 | 2 | 1 | 2 | 7:7 | 0 | 5:5 |
| 9 |
|
Real Valladolid | 5 | 2 | 0 | 3 | 7:6 | 1 | 4:6 |
| 10 |
|
UP Langreo | 5 | 2 | 0 | 3 | 5:6 | -1 | 4:6 |
| 11 |
|
CD Logroñés | 5 | 2 | 0 | 3 | 4:13 | -9 | 4:6 |
| 12 |
|
Gimnástica Torrelavega | 5 | 2 | 0 | 3 | 6:11 | -5 | 4:6 |
| 13 |
|
Burgos CF | 5 | 1 | 1 | 3 | 3:8 | -5 | 3:7 |
| 14 |
|
SD Indautxu | 5 | 1 | 1 | 3 | 2:8 | -6 | 3:7 |
| 15 |
|
CA Osasuna | 5 | 1 | 1 | 3 | 6:12 | -6 | 3:7 |
| 16 |
|
CD Tenerife | 5 | 1 | 1 | 3 | 5:9 | -4 | 3:7 |
| 2 | |||||||||
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Levante UD | 5 | 4 | 0 | 1 | 7:3 | 4 | 8:2 |
| 2 |
|
CD Málaga | 5 | 3 | 2 | 0 | 6:3 | 3 | 8:2 |
| 3 |
|
Real Betis | 5 | 3 | 1 | 1 | 11:3 | 8 | 7:3 |
| 4 |
|
CD Castellón | 5 | 3 | 1 | 1 | 5:2 | 3 | 7:3 |
| 5 |
|
RCD Mallorca | 5 | 2 | 1 | 2 | 6:5 | 1 | 5:5 |
| 6 |
|
Recreativo Huelva | 5 | 2 | 1 | 2 | 4:4 | 0 | 5:5 |
| 7 |
|
CA Ceuta | 5 | 2 | 1 | 2 | 5:6 | -1 | 5:5 |
| 8 |
|
CD Mestalla | 5 | 2 | 1 | 2 | 10:16 | -6 | 5:5 |
| 9 |
|
CE Europa | 5 | 2 | 1 | 2 | 3:4 | -1 | 5:5 |
| 10 |
|
Real Murcia | 5 | 2 | 1 | 2 | 10:6 | 4 | 5:5 |
| 11 |
|
Algeciras CF | 5 | 1 | 2 | 2 | 5:7 | -2 | 4:6 |
| 12 |
|
CF Badalona | 5 | 1 | 2 | 2 | 3:5 | -2 | 4:6 |
| 13 |
|
CD Condal | 5 | 1 | 1 | 3 | 6:8 | -2 | 3:7 |
| 14 |
|
CD Constància | 5 | 1 | 1 | 3 | 4:6 | -2 | 3:7 |
| 15 |
|
UE Lleida | 5 | 1 | 1 | 3 | 2:5 | -3 | 3:7 |
| 16 |
|
Cádiz CF | 5 | 0 | 3 | 2 | 3:7 | -4 | 3:7 |
