| 1. Ronde | 05.08.2005 | Club Brugge KV | - | Excelsior Mouscron | 2:0 | ||||
| 2. Ronde | 13.08.2005 | Excelsior Mouscron | - | Sporting Lokeren | 0:2 | ||||
| 3. Ronde | 20.08.2005 | Sporting Charleroi | - | Excelsior Mouscron | 1:0 | ||||
| 4. Ronde | 27.08.2005 | Excelsior Mouscron | - | KVC Westerlo | 1:0 | ||||
| 5. Ronde | 10.09.2005 | RSC Anderlecht | - | Excelsior Mouscron | 3:1 | ||||
| 7. Ronde | 21.09.2005 | SV Zulte Waregem | - | Excelsior Mouscron | 4:1 |  |
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| 8. Ronde | 24.09.2005 | Excelsior Mouscron | - | RAA La Louviére | 2:1 | |
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| 9. Ronde | 02.10.2005 | Cercle Brugge | - | Excelsior Mouscron | 1:0 | ||||
| 11. Ronde | 22.10.2005 | KRC Genk | - | Excelsior Mouscron | 1:0 | ||||
| 13. Ronde | 05.11.2005 | Excelsior Mouscron | - | FC Brussels | 1:1 | ||||
| 19. Ronde | 21.01.2006 | Sporting Lokeren | - | Excelsior Mouscron | 1:1 | ||||
| 20. Ronde | 28.01.2006 | Excelsior Mouscron | - | Sporting Charleroi | 0:1 | ||||
| 21. Ronde | 04.02.2006 | KVC Westerlo | - | Excelsior Mouscron | 0:5 | |
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| 22. Ronde | 11.02.2006 | Excelsior Mouscron | - | RSC Anderlecht | 0:1 | ||||
| 32. Ronde | 22.04.2006 | Lierse SK (old) | - | Excelsior Mouscron | 2:0 |
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