| 1. Ronde | 12.09.2021 | Volos NFC | - | Lamia | 2:1 | ||||
| 2. Ronde | 19.09.2021 | Apollon Smyrnis | - | Volos NFC | 1:3 | ||||
| 4. Ronde | 26.09.2021 | Panathinaikos | - | Volos NFC | 5:1 | ||||
| 8. Ronde | 01.11.2021 | Ionikos Nikea | - | Volos NFC | 1:1 | ||||
| 9. Ronde | 07.11.2021 | Volos NFC | - | Aris Saloniki | 1:2 | ||||
| 11. Ronde | 28.11.2021 | Olympiakos | - | Volos NFC | 2:1 |  |
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| 12. Ronde | 04.12.2021 | Volos NFC | - | Panetolikos | 1:2 | |
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| 13. Ronde | 11.12.2021 | PAS Giannina | - | Volos NFC | 3:2 |
Polen