| 1. Ronde | 19.09.2020 | Sassuolo Calcio [A-jun] | - | Empoli FC [A-jun] | 3:2 | ||||
| 2. Ronde | 25.09.2020 | Empoli FC [A-jun] | - | Juventus [A-jun] | 0:2 | ||||
| 3. Ronde | 04.10.2020 | Atalanta [A-jun] | - | Empoli FC [A-jun] | 2:4 | ||||
| 20. Ronde | 24.04.2021 | ACF Fiorentina [A-jun] | - | Empoli FC [A-jun] | 0:4 | ||||
| 13. Ronde | 28.04.2021 | Torino FC [A-jun] | - | Empoli FC [A-jun] | 0:4 | ||||
| 21. Ronde | 02.05.2021 | Empoli FC [A-jun] | - | AC Milan [A-jun] | 1:1 | ||||
| 17. Ronde | 05.05.2021 | Juventus [A-jun] | - | Empoli FC [A-jun] | 1:1 | ||||
| 22. Ronde | 08.05.2021 | Bologna FC [A-jun] | - | Empoli FC [A-jun] | 1:4 | ||||
| 18. Ronde | 12.05.2021 | Empoli FC [A-jun] | - | Atalanta [A-jun] | 1:2 | ||||
| 24. Ronde | 22.05.2021 | Empoli FC [A-jun] | - | Lazio Roma [A-jun] | 3:0 | ||||
| 25. Ronde | 26.05.2021 | Ascoli Calcio [A-jun] | - | Empoli FC [A-jun] | 1:3 | ||||
| 26. Ronde | 29.05.2021 | Empoli FC [A-jun] | - | AS Roma [A-jun] | 0:1 |  |
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| 30. Ronde | 16.06.2021 | Empoli FC [A-jun] | - | SPAL 2013 Ferrara [A-jun] | 3:0 |
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