| 2. Ronde | 27.09.2020 | SSC Napoli | - | Genoa CFC | 6:0 | ||||
| 10. Ronde | 06.12.2020 | FC Crotone | - | SSC Napoli | 0:4 | ||||
| 13. Ronde | 20.12.2020 | Lazio | - | SSC Napoli | 2:0 | ||||
| 14. Ronde | 23.12.2020 | SSC Napoli | - | Torino FC | 1:1 | ||||
| 15. Ronde | 03.01.2021 | Cagliari Calcio | - | SSC Napoli | 1:4 | ||||
| 16. Ronde | 06.01.2021 | SSC Napoli | - | Spezia Calcio | 1:2 | ||||
| 17. Ronde | 10.01.2021 | Udinese Calcio | - | SSC Napoli | 1:2 | ||||
| 19. Ronde | 24.01.2021 | Hellas Verona | - | SSC Napoli | 3:1 | ||||
| 20. Ronde | 31.01.2021 | SSC Napoli | - | Parma Calcio 1913 | 2:0 | ||||
| 21. Ronde | 06.02.2021 | Genoa CFC | - | SSC Napoli | 2:1 | ||||
| 22. Ronde | 13.02.2021 | SSC Napoli | - | Juventus | 1:0 | ||||
| 23. Ronde | 21.02.2021 | Atalanta | - | SSC Napoli | 4:2 | ||||
| 24. Ronde | 28.02.2021 | SSC Napoli | - | Benevento Calcio | 2:0 | ||||
| 25. Ronde | 03.03.2021 | Sassuolo Calcio | - | SSC Napoli | 3:3 | ||||
| 27. Ronde | 14.03.2021 | AC Milan | - | SSC Napoli | 0:1 |  |
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| 28. Ronde | 21.03.2021 | AS Roma | - | SSC Napoli | 0:2 | ||||
| 29. Ronde | 03.04.2021 | SSC Napoli | - | FC Crotone | 4:3 |
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