| 1. Ronde | 01.08.2021 | Motherwell FC | - | Hibernian FC | 2:3 | ||||
| 2. Ronde | 08.08.2021 | St. Johnstone FC | - | Motherwell FC | 1:1 | ||||
| 5. Ronde | 11.09.2021 | Motherwell FC | - | Aberdeen FC | 2:0 | ||||
| 12. Ronde | 31.10.2021 | Motherwell FC | - | Rangers FC | 1:6 | ||||
| 13. Ronde | 06.11.2021 | Aberdeen FC | - | Motherwell FC | 0:2 |  |
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| 14. Ronde | 20.11.2021 | Motherwell FC | - | Heart of Midlothian | 2:0 | ||||
| 15. Ronde | 27.11.2021 | Dundee FC | - | Motherwell FC | 3:0 | ||||
| 16. Ronde | 30.11.2021 | Motherwell FC | - | Dundee United | 1:0 |  |
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| 18. Ronde | 12.12.2021 | Celtic FC | - | Motherwell FC | 1:0 | ||||
| 20. Ronde | 26.12.2021 | Motherwell FC | - | Livingston FC | 2:1 | ||||
| 21. Ronde | 18.01.2022 | Ross County FC | - | Motherwell FC | 3:1 | ||||
| 23. Ronde | 26.01.2022 | Motherwell FC | - | Hibernian FC | 0:0 | ||||
| 24. Ronde | 29.01.2022 | Heart of Midlothian | - | Motherwell FC | 2:0 |
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