| 5. Ronde | 13.09.2021 | CS Marítimo | - | FC Arouca | 2:2 |  |
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| 6. Ronde | 18.09.2021 | FC Arouca | - | Vitória Guimarães | 2:2 | ||||
| 7. Ronde | 25.09.2021 | Moreirense FC | - | FC Arouca | 2:1 | |
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| 8. Ronde | 02.10.2021 | FC Arouca | - | Sporting CP | 1:2 | ||||
| 9. Ronde | 24.10.2021 | Paços de Ferreira | - | FC Arouca | 0:0 | ||||
| 10. Ronde | 29.10.2021 | FC Arouca | - | CD Tondela | 2:0 | |
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| 11. Ronde | 05.11.2021 | Gil Vicente | - | FC Arouca | 1:1 | |
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| 12. Ronde | 27.11.2021 | FC Arouca | - | Boavista | 2:1 | ||||
| 13. Ronde | 05.12.2021 | CD Santa Clara | - | FC Arouca | 2:1 | ||||
| 14. Ronde | 13.12.2021 | FC Arouca | - | FC Vizela | 1:4 | ||||
| 15. Ronde | 18.12.2021 | Portimonense SC | - | FC Arouca | 1:1 | |
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| 17. Ronde | 09.01.2022 | Belenenses SAD | - | FC Arouca | 2:1 | ||||
| 19. Ronde | 21.01.2022 | FC Arouca | - | SL Benfica | 0:2 | |
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| 18. Ronde | 27.01.2022 | GD Estoril | - | FC Arouca | 1:2 |  |
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| 20. Ronde | 31.01.2022 | FC Famalicão | - | FC Arouca | 0:0 | ||||
| 21. Ronde | 06.02.2022 | FC Arouca | - | FC Porto | 0:2 | |
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| 22. Ronde | 14.02.2022 | FC Arouca | - | CS Marítimo | 0:3 | ||||
| 23. Ronde | 19.02.2022 | Vitória Guimarães | - | FC Arouca | 1:3 | |
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| 24. Ronde | 26.02.2022 | FC Arouca | - | Moreirense FC | 1:1 | |
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