| 1. Ronde | 17.08.2013 | Real Valladolid | - | Athletic Club | 1:2 | ||||
| 2. Ronde | 23.08.2013 | Athletic Club | - | CA Osasuna | 2:0 | ||||
| 3. Ronde | 01.09.2013 | Real Madrid | - | Athletic Club | 3:1 | ||||
| 4. Ronde | 16.09.2013 | Athletic Club | - | Celta de Vigo | 3:2 | ||||
| 12. Ronde | 03.11.2013 | Atlético Madrid | - | Athletic Club | 2:0 |  |
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| 20. Ronde | 20.01.2014 | Athletic Club | - | Real Valladolid | 4:2 |  |
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| 24. Ronde | 16.02.2014 | Athletic Club | - | Espanyol | 1:2 | ||||
| 30. Ronde | 25.03.2014 | Elche CF | - | Athletic Club | 0:0 | ||||
| 32. Ronde | 07.04.2014 | Levante UD | - | Athletic Club | 1:2 | |
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| 33. Ronde | 14.04.2014 | Athletic Club | - | Málaga CF | 3:0 | ||||
| 34. Ronde | 20.04.2014 | FC Barcelona | - | Athletic Club | 2:1 | ||||
| 35. Ronde | 27.04.2014 | Athletic Club | - | Sevilla FC | 3:1 | ||||
| 36. Ronde | 02.05.2014 | Rayo Vallecano | - | Athletic Club | 0:3 | ||||
| 38. Ronde | 18.05.2014 | UD Almería | - | Athletic Club | 0:0 | |
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