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| 01.11.2013 | 21:00 | FC Barcelona | - | Espanyol | 1:0 (0:0) | |
| 02.11.2013 | 16:00 | Real Sociedad | - | CA Osasuna | 5:0 (1:0) | |
| 18:00 | UD Almería | - | Real Valladolid | 1:0 (1:0) | ||
| 20:00 | Rayo Vallecano | - | Real Madrid | 2:3 (0:2) | ||
| 22:00 | Sevilla FC | - | Celta de Vigo | 0:1 (0:0) | ||
| 03.11.2013 | 12:00 | Getafe CF | - | Valencia CF | 0:1 (0:1) | |
| 17:00 | Atlético Madrid | - | Athletic Bilbao | 2:0 (2:0) | ||
| 19:00 | Levante UD | - | Granada CF | 0:1 (0:0) | ||
| 21:00 | Málaga CF | - | Real Betis | 3:2 (1:1) | ||
| 04.11.2013 | 22:00 | Elche CF | - | Villarreal CF | 0:1 (0:0) |
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
FC Barcelona | 12 | 11 | 1 | 0 | 34:7 | 27 | 34 |
| 2 |
|
Atlético Madrid | 12 | 11 | 0 | 1 | 30:8 | 22 | 33 |
| 3 |
|
Real Madrid | 12 | 9 | 1 | 2 | 30:16 | 14 | 28 |
| 4 |
|
Villarreal CF | 12 | 7 | 2 | 3 | 20:12 | 8 | 23 |
| 5 |
|
Athletic Bilbao | 12 | 6 | 2 | 4 | 18:17 | 1 | 20 |
| 6 |
|
Getafe CF | 12 | 6 | 1 | 5 | 16:13 | 3 | 19 |
| 7 |
|
Levante UD | 12 | 4 | 5 | 3 | 12:15 | -3 | 17 |
| 8 |
|
Real Sociedad | 12 | 4 | 5 | 3 | 18:12 | 6 | 17 |
| 9 |
|
Valencia CF | 12 | 5 | 1 | 6 | 15:19 | -4 | 16 |
| 10 |
|
Espanyol | 12 | 4 | 3 | 5 | 12:15 | -3 | 15 |
| 11 |
|
Granada CF | 12 | 4 | 2 | 6 | 8:12 | -4 | 14 |
| 12 |
|
Málaga CF | 12 | 3 | 4 | 5 | 14:16 | -2 | 13 |
| 13 |
|
Elche CF | 12 | 3 | 4 | 5 | 12:16 | -4 | 13 |
| 14 |
|
Sevilla FC | 12 | 3 | 4 | 5 | 20:25 | -5 | 13 |
| 15 |
|
Celta de Vigo | 12 | 3 | 3 | 6 | 14:16 | -2 | 12 |
| 16 |
|
Real Valladolid | 12 | 2 | 5 | 5 | 14:18 | -4 | 11 |
| 17 |
|
CA Osasuna | 12 | 3 | 1 | 8 | 10:21 | -11 | 10 |
| 18 |
|
Real Betis | 12 | 2 | 3 | 7 | 11:20 | -9 | 9 |
| 19 |
|
Rayo Vallecano | 12 | 3 | 0 | 9 | 10:30 | -20 | 9 |
| 20 |
|
UD Almería | 12 | 2 | 3 | 7 | 14:24 | -10 | 9 |
| Champions League | |
| Champions League Kwali. | |
| Europa League Kwali. | |
| Degradatie |
