| 1. Ronde | 30.07.2022 | Ayr United | - | Arbroath FC | 0:0 | ||||
| 2. Ronde | 05.08.2022 | Queen's Park FC | - | Ayr United | 2:3 | ||||
| 17. Ronde | 03.12.2022 | Ayr United | - | Raith Rovers | 2:0 | ||||
| 19. Ronde | 23.12.2022 | Ayr United | - | Dundee FC | 0:2 | ||||
| 21. Ronde | 07.01.2023 | Ayr United | - | Hamilton Academical | 1:0 | ||||
| 23. Ronde | 27.01.2023 | Cove Rangers | - | Ayr United | 0:5 |  |
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| 24. Ronde | 03.02.2023 | Queen's Park FC | - | Ayr United | 2:0 | ||||
| 25. Ronde | 18.02.2023 | Ayr United | - | Partick Thistle | 0:1 | ||||
| 29. Ronde | 18.03.2023 | Hamilton Academical | - | Ayr United | 0:2 | ||||
| 30. Ronde | 24.03.2023 | Ayr United | - | Cove Rangers | 3:0 | ||||
| 32. Ronde | 08.04.2023 | Ayr United | - | Greenock Morton FC | 1:1 | ||||
| 36. Ronde | 05.05.2023 | Inverness CT | - | Ayr United | 1:2 |
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