| 10. Ronde | 01.10.2000 | Heart of Midlothian | - | Motherwell FC | 3:0 |  |
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| 11. Ronde | 14.10.2000 | Dundee United | - | Heart of Midlothian | 0:4 | ||||
| 12. Ronde | 22.10.2000 | Hibernian FC | - | Heart of Midlothian | 6:2 | ||||
| 13. Ronde | 28.10.2000 | Heart of Midlothian | - | St. Johnstone FC | 0:3 | ||||
| 16. Ronde | 18.11.2000 | Celtic FC | - | Heart of Midlothian | 6:1 |  |
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| 17. Ronde | 25.11.2000 | Heart of Midlothian | - | Dundee FC | 3:1 | |
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| 18. Ronde | 29.11.2000 | Dunfermline Athletic | - | Heart of Midlothian | 1:0 | ||||
| 19. Ronde | 03.12.2000 | Heart of Midlothian | - | Rangers FC | 0:1 | ||||
| 20. Ronde | 09.12.2000 | Kilmarnock FC | - | Heart of Midlothian | 0:3 | ||||
| 21. Ronde | 16.12.2000 | Motherwell FC | - | Heart of Midlothian | 2:0 | ||||
| 24. Ronde | 30.12.2000 | St. Johnstone FC | - | Heart of Midlothian | 2:2 | |
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| 25. Ronde | 02.01.2001 | Aberdeen FC | - | Heart of Midlothian | 1:0 | ||||
| 27. Ronde | 04.02.2001 | Heart of Midlothian | - | Celtic FC | 0:3 | |
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| 29. Ronde | 24.02.2001 | Heart of Midlothian | - | Dunfermline Athletic | 7:1 | ||||
| 30. Ronde | 03.03.2001 | Rangers FC | - | Heart of Midlothian | 2:0 |
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