| 8. Ronde | 01.10.2022 | Anadia FC [A-jun] | - | Gil Vicente [A-jun] | 1:3 |  |
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| 9. Ronde | 08.10.2022 | Gil Vicente [A-jun] | - | Sporting Braga [A-jun] | 2:1 | ||||
| 10. Ronde | 15.10.2022 | FC Famalicão [A-jun] | - | Gil Vicente [A-jun] | 2:1 | ||||
| 11. Ronde | 22.10.2022 | Gil Vicente [A-jun] | - | Rio Ave FC [A-jun] | 0:1 |  |
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| 12. Ronde | 29.10.2022 | Gil Vicente [A-jun] | - | CD Tondela [A-jun] | 4:0 | ||||
| 13. Ronde | 06.11.2022 | Paços de Ferreira [A-jun] | - | Gil Vicente [A-jun] | 2:1 | |
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| 14. Ronde | 12.11.2022 | Boavista [A-jun] | - | Gil Vicente [A-jun] | 1:4 | |
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| 15. Ronde | 19.11.2022 | Gil Vicente [A-jun] | - | Gondomar SC [A-jun] | 3:4 | ||||
| 16. Ronde | 03.12.2022 | Vitória Guimarães [A-jun] | - | Gil Vicente [A-jun] | 2:2 | |
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| 17. Ronde | 08.12.2022 | Gil Vicente [A-jun] | - | FC Vizela [A-jun] | 2:2 | ||||
| 18. Ronde | 17.12.2022 | FC Porto [A-jun] | - | Gil Vicente [A-jun] | 1:2 | |
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| 20. Ronde | 14.01.2023 | Sporting Braga [A-jun] | - | Gil Vicente [A-jun] | 3:3 | |
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| 21. Ronde | 21.01.2023 | Gil Vicente [A-jun] | - | FC Famalicão [A-jun] | 1:1 |  |
Oekraïne