| 1. Ronde | 11.09.1966 | Athletic Club | - | Atlético Madrid | 1:0 | ||||
| 2. Ronde | 18.09.1966 | CE Sabadell | - | Athletic Club | 1:0 | ||||
| 3. Ronde | 25.09.1966 | Athletic Club | - | Elche CF | 2:1 | ||||
| 4. Ronde | 02.10.1966 | Pontevedra CF | - | Athletic Club | 1:1 | ||||
| 5. Ronde | 09.10.1966 | Athletic Club | - | Espanyol | 1:3 | ||||
| 6. Ronde | 16.10.1966 | Granada CF | - | Athletic Club | 1:1 | ||||
| 7. Ronde | 30.10.1966 | Athletic Club | - | Real Zaragoza | 2:3 | ||||
| 8. Ronde | 06.11.1966 | Sevilla FC | - | Athletic Club | 1:1 |  |
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| 17. Ronde | 15.01.1967 | Athletic Club | - | CE Sabadell | 1:1 | ||||
| 18. Ronde | 22.01.1967 | Elche CF | - | Athletic Club | 1:1 | ||||
| 26. Ronde | 26.03.1967 | Athletic Club | - | UD Las Palmas | 3:0 | ||||
| 27. Ronde | 02.04.1967 | FC Barcelona | - | Athletic Club | 3:1 | ||||
| 28. Ronde | 08.04.1967 | Athletic Club | - | Deportivo La Coruña | 4:0 | ||||
| 29. Ronde | 15.04.1967 | Valencia CF | - | Athletic Club | 1:0 |
Spanje