| 1. Ronde | 28.08.2010 | Hércules CF | - | Athletic Club | 0:1 |  |
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| 2. Ronde | 11.09.2010 | Athletic Club | - | Atlético Madrid | 1:2 | ||||
| 3. Ronde | 18.09.2010 | Sporting Gijón | - | Athletic Club | 2:2 | |
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| 4. Ronde | 21.09.2010 | Athletic Club | - | RCD Mallorca | 3:0 | ||||
| 5. Ronde | 25.09.2010 | Athletic Club | - | FC Barcelona | 1:3 | |
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| 6. Ronde | 02.10.2010 | Valencia CF | - | Athletic Club | 2:1 | |
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| 10. Ronde | 07.11.2010 | Villarreal CF | - | Athletic Club | 4:1 |  |
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| 12. Ronde | 20.11.2010 | Real Madrid | - | Athletic Club | 5:1 | ||||
| 13. Ronde | 28.11.2010 | Athletic Club | - | CA Osasuna | 1:0 | ||||
| 14. Ronde | 05.12.2010 | Real Sociedad | - | Athletic Club | 2:0 |
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