| 2. Ronde | 24.08.2013 | Real Madrid Castilla | - | AD Alcorcón | 0:1 |  |
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| 3. Ronde | 31.08.2013 | Hércules CF | - | Real Madrid Castilla | 2:1 | ||||
| 5. Ronde | 15.09.2013 | FC Barcelona B | - | Real Madrid Castilla | 2:0 | ||||
| 6. Ronde | 21.09.2013 | Real Madrid Castilla | - | Real Zaragoza | 1:2 | ||||
| 8. Ronde | 06.10.2013 | Real Madrid Castilla | - | CD Lugo | 2:0 | ||||
| 10. Ronde | 20.10.2013 | RCD Mallorca | - | Real Madrid Castilla | 2:0 | ||||
| 11. Ronde | 27.10.2013 | Real Madrid Castilla | - | SD Ponferradina | 1:1 | ||||
| 18. Ronde | 14.12.2013 | UD Las Palmas | - | Real Madrid Castilla | 0:2 | ||||
| 23. Ronde | 26.01.2014 | AD Alcorcón | - | Real Madrid Castilla | 0:2 | ||||
| 24. Ronde | 01.02.2014 | Real Madrid Castilla | - | Hércules CF | 4:0 | ||||
| 27. Ronde | 23.02.2014 | Real Zaragoza | - | Real Madrid Castilla | 0:2 |
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