| 1. Ronde | 19.08.2024 | Real Valladolid | - | Espanyol | 1:0 | ||||
| 6. Ronde | 21.09.2024 | Real Valladolid | - | Real Sociedad | 0:0 | ||||
| 7. Ronde | 24.09.2024 | Sevilla FC | - | Real Valladolid | 2:1 |  |
|||
| 8. Ronde | 27.09.2024 | Real Valladolid | - | RCD Mallorca | 1:2 | ||||
| 9. Ronde | 05.10.2024 | Real Valladolid | - | Rayo Vallecano | 1:2 | |
|||
| 10. Ronde | 18.10.2024 | Deportivo Alavés | - | Real Valladolid | 2:3 | ||||
| 11. Ronde | 26.10.2024 | Real Valladolid | - | Villarreal CF | 1:2 | |
|||
| 12. Ronde | 02.11.2024 | CA Osasuna | - | Real Valladolid | 1:0 | ||||
| 13. Ronde | 10.11.2024 | Real Valladolid | - | Athletic Club | 1:1 | |
|||
| 18. Ronde | 20.12.2024 | Girona FC | - | Real Valladolid | 3:0 | ||||
| 19. Ronde | 11.01.2025 | Real Valladolid | - | Real Betis | 1:0 | ||||
| 21. Ronde | 25.01.2025 | Real Valladolid | - | Real Madrid | 0:3 | ||||
| 22. Ronde | 01.02.2025 | Villarreal CF | - | Real Valladolid | 5:1 | ||||
| 23. Ronde | 07.02.2025 | Rayo Vallecano | - | Real Valladolid | 1:0 | ||||
| 24. Ronde | 16.02.2025 | Real Valladolid | - | Sevilla FC | 0:4 | ||||
| 25. Ronde | 23.02.2025 | Athletic Club | - | Real Valladolid | 7:1 | ||||
| 27. Ronde | 08.03.2025 | Valencia CF | - | Real Valladolid | 2:1 | ||||
| 29. Ronde | 29.03.2025 | Real Sociedad | - | Real Valladolid | 2:1 | |
Spanje