| 2. Ronde | 30.09.1945 | Sporting Gijón | - | Hércules CF | 2:0 |  |
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| 3. Ronde | 07.10.1945 | Celta de Vigo | - | Sporting Gijón | 2:3 | ||||
| 4. Ronde | 14.10.1945 | Sporting Gijón | - | CD Castellón | 2:0 | |
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| 5. Ronde | 21.10.1945 | Sevilla FC | - | Sporting Gijón | 3:2 | ||||
| 6. Ronde | 28.10.1945 | Sporting Gijón | - | Real Madrid | 1:1 | ||||
| 7. Ronde | 04.11.1945 | Sporting Gijón | - | Espanyol | 4:1 | ||||
| 8. Ronde | 18.11.1945 | CD Alcoyano | - | Sporting Gijón | 4:1 | ||||
| 9. Ronde | 25.11.1945 | Sporting Gijón | - | Atlético Aviación | 3:2 | |
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| 10. Ronde | 02.12.1945 | Athletic Club | - | Sporting Gijón | 2:3 | |
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| 11. Ronde | 09.12.1945 | Sporting Gijón | - | Valencia CF | 1:2 | ||||
| 13. Ronde | 30.12.1945 | Sporting Gijón | - | Real Oviedo | 1:0 | ||||
| 14. Ronde | 06.01.1946 | Sporting Gijón | - | FC Barcelona | 2:0 | ||||
| 19. Ronde | 10.02.1946 | Real Madrid | - | Sporting Gijón | 2:2 | ||||
| 26. Ronde | 31.03.1946 | Real Oviedo | - | Sporting Gijón | 2:2 | |
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