| 1. Ronde | 01.09.1985 | Real Zaragoza | - | Hércules CF | 1:0 | ||||
| 2. Ronde | 04.09.1985 | Hércules CF | - | Atlético Madrid | 2:2 | ||||
| 3. Ronde | 08.09.1985 | CA Osasuna | - | Hércules CF | 1:0 | ||||
| 4. Ronde | 15.09.1985 | Hércules CF | - | Athletic Club | 0:1 | ||||
| 5. Ronde | 29.09.1985 | Sevilla FC | - | Hércules CF | 0:0 | ||||
| 6. Ronde | 06.10.1985 | Hércules CF | - | UD Las Palmas | 2:0 | ||||
| 7. Ronde | 13.10.1985 | Hércules CF | - | FC Barcelona | 1:2 | ||||
| 8. Ronde | 20.10.1985 | Cádiz CF | - | Hércules CF | 2:0 | ||||
| 9. Ronde | 27.10.1985 | Hércules CF | - | Real Valladolid | 1:0 | ||||
| 10. Ronde | 02.11.1985 | Real Madrid | - | Hércules CF | 4:0 | ||||
| 11. Ronde | 10.11.1985 | Hércules CF | - | Celta de Vigo | 5:2 | ||||
| 15. Ronde | 08.12.1985 | Hércules CF | - | Valencia CF | 3:2 | ||||
| 16. Ronde | 15.12.1985 | Espanyol | - | Hércules CF | 4:1 | ||||
| 30. Ronde | 23.03.1986 | Real Sociedad | - | Hércules CF | 6:0 | ||||
| 31. Ronde | 30.03.1986 | Hércules CF | - | Real Betis | 2:3 | ||||
| 32. Ronde | 06.04.1986 | Valencia CF | - | Hércules CF | 3:1 | ||||
| 33. Ronde | 13.04.1986 | Hércules CF | - | Espanyol | 1:1 | ||||
| 34. Ronde | 20.04.1986 | Racing Santander | - | Hércules CF | 4:1 |
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