| 2. Ronde | 23.08.2013 | Athletic Club | - | CA Osasuna | 2:0 | ||||
| 3. Ronde | 01.09.2013 | Real Madrid | - | Athletic Club | 3:1 |  |
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| 4. Ronde | 16.09.2013 | Athletic Club | - | Celta de Vigo | 3:2 | ||||
| 5. Ronde | 23.09.2013 | Espanyol | - | Athletic Club | 3:2 | |
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| 6. Ronde | 26.09.2013 | Athletic Club | - | Real Betis | 2:1 | ||||
| 7. Ronde | 30.09.2013 | Granada CF | - | Athletic Club | 2:0 | ||||
| 13. Ronde | 09.11.2013 | Athletic Club | - | Levante UD | 2:1 | ||||
| 14. Ronde | 25.11.2013 | Málaga CF | - | Athletic Club | 1:2 | ||||
| 15. Ronde | 01.12.2013 | Athletic Club | - | FC Barcelona | 1:0 | ||||
| 16. Ronde | 15.12.2013 | Sevilla FC | - | Athletic Club | 1:1 | ||||
| 17. Ronde | 22.12.2013 | Athletic Club | - | Rayo Vallecano | 2:1 | ||||
| 18. Ronde | 05.01.2014 | Real Sociedad | - | Athletic Club | 2:0 | ||||
| 19. Ronde | 11.01.2014 | Athletic Club | - | UD Almería | 6:1 | |
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| 20. Ronde | 20.01.2014 | Athletic Club | - | Real Valladolid | 4:2 | |
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| 21. Ronde | 26.01.2014 | CA Osasuna | - | Athletic Club | 1:5 | |
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| 22. Ronde | 02.02.2014 | Athletic Club | - | Real Madrid | 1:1 | |
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| 23. Ronde | 10.02.2014 | Celta de Vigo | - | Athletic Club | 0:0 | ||||
| 24. Ronde | 16.02.2014 | Athletic Club | - | Espanyol | 1:2 |
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