| 2. Ronde | 20.09.1964 | Real Oviedo | - | Athletic Club | 1:0 | ||||
| 3. Ronde | 27.09.1964 | Athletic Club | - | Valencia CF | 3:2 | ||||
| 13. Ronde | 13.12.1964 | Espanyol | - | Athletic Club | 3:1 | ||||
| 19. Ronde | 24.01.1965 | Athletic Club | - | Real Zaragoza | 3:1 | ||||
| 20. Ronde | 31.01.1965 | Real Betis | - | Athletic Club | 1:2 | ||||
| 21. Ronde | 07.02.1965 | Athletic Club | - | FC Barcelona | 0:0 | ||||
| 22. Ronde | 14.02.1965 | Atlético Madrid | - | Athletic Club | 4:0 | ||||
| 23. Ronde | 21.02.1965 | Athletic Club | - | Deportivo La Coruña | 0:0 | ||||
| 30. Ronde | 18.04.1965 | Athletic Club | - | Córdoba CF | 1:0 |
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