| 1. Ronde | 23.09.1945 | Hércules CF | - | Sevilla FC | 1:2 |  |
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| 2. Ronde | 30.09.1945 | Sporting Gijón | - | Hércules CF | 2:0 | ||||
| 3. Ronde | 07.10.1945 | Hércules CF | - | Espanyol | 0:0 | ||||
| 5. Ronde | 21.10.1945 | Hércules CF | - | Atlético Aviación | 3:2 | ||||
| 6. Ronde | 28.10.1945 | Athletic Club | - | Hércules CF | 6:0 | ||||
| 7. Ronde | 04.11.1945 | Hércules CF | - | Valencia CF | 2:1 | |
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| 10. Ronde | 02.12.1945 | FC Barcelona | - | Hércules CF | 5:3 | ||||
| 11. Ronde | 09.12.1945 | Real Madrid | - | Hércules CF | 2:0 | ||||
| 12. Ronde | 16.12.1945 | Hércules CF | - | Celta de Vigo | 1:4 | ||||
| 25. Ronde | 24.03.1946 | Celta de Vigo | - | Hércules CF | 4:2 |
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