| 1. Ronde | 27.08.2021 | CD Alcoyano | - | Real Betis B | 1:0 |  |
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| 2. Ronde | 04.09.2021 | Linares Deportivo | - | CD Alcoyano | 1:1 | ||||
| 3. Ronde | 11.09.2021 | CD Alcoyano | - | CE Sabadell | 1:1 | ||||
| 4. Ronde | 19.09.2021 | Sevilla Atlético | - | CD Alcoyano | 1:3 | |
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| 6. Ronde | 02.10.2021 | CD Alcoyano | - | San Fernando CD | 0:2 | ||||
| 7. Ronde | 10.10.2021 | Atlético Sanluqueño CF | - | CD Alcoyano | 2:2 | ||||
| 8. Ronde | 15.10.2021 | CD Alcoyano | - | UCAM Murcia CF | 3:2 | ||||
| 10. Ronde | 31.10.2021 | CD Alcoyano | - | Algeciras CF | 0:0 | ||||
| 11. Ronde | 07.11.2021 | Villarreal CF B | - | CD Alcoyano | 0:1 | |
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| 12. Ronde | 13.11.2021 | CD Alcoyano | - | Atlético Baleares | 0:0 | ||||
| 13. Ronde | 20.11.2021 | FC Andorra | - | CD Alcoyano | 1:2 | ||||
| 14. Ronde | 28.11.2021 | CD Alcoyano | - | UE Cornellà | 2:0 | ||||
| 15. Ronde | 04.12.2021 | Albacete | - | CD Alcoyano | 2:0 | ||||
| 16. Ronde | 11.12.2021 | CD Alcoyano | - | UE Costa Brava | 0:1 | ||||
| 17. Ronde | 18.12.2021 | RB Linense | - | CD Alcoyano | 1:0 | ||||
| 25. Ronde | 26.02.2022 | CD Alcoyano | - | FC Barcelona B | 2:3 |
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