| 2. Ronde | 18.08.2023 | Real Zaragoza | - | Real Valladolid | 1:0 | ||||
| 4. Ronde | 01.09.2023 | Albacete | - | Real Valladolid | 2:0 |  |
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| 5. Ronde | 10.09.2023 | Real Valladolid | - | Elche CF | 1:1 |  |
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| 10. Ronde | 08.10.2023 | Real Valladolid | - | CD Mirandés | 3:2 | |
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| 11. Ronde | 14.10.2023 | Espanyol | - | Real Valladolid | 2:0 | |
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| 12. Ronde | 22.10.2023 | Real Valladolid | - | FC Andorra | 2:0 |  |
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| 13. Ronde | 27.10.2023 | SD Eibar | - | Real Valladolid | 5:1 | ||||
| 16. Ronde | 17.11.2023 | Real Valladolid | - | CD Leganés | 1:1 | ||||
| 19. Ronde | 09.12.2023 | Real Valladolid | - | SD Amorebieta | 2:1 | ||||
| 20. Ronde | 18.12.2023 | Villarreal CF B | - | Real Valladolid | 1:0 | ||||
| 21. Ronde | 21.12.2023 | Real Valladolid | - | Racing Ferrol | 0:1 |
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