| 1. Ronde | 05.09.1965 | Real Zaragoza | - | Atlético Madrid | 2:2 |  |
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| 2. Ronde | 12.09.1965 | Atlético Madrid | - | Elche CF | 3:0 | ||||
| 3. Ronde | 19.09.1965 | Sevilla FC | - | Atlético Madrid | 1:1 | ||||
| 4. Ronde | 26.09.1965 | Atlético Madrid | - | CD Málaga | 1:0 | ||||
| 5. Ronde | 03.10.1965 | Athletic Club | - | Atlético Madrid | 0:2 | |
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| 6. Ronde | 10.10.1965 | Atlético Madrid | - | Real Madrid | 1:1 | ||||
| 13. Ronde | 12.12.1965 | Córdoba CF | - | Atlético Madrid | 0:1 | ||||
| 20. Ronde | 23.01.1966 | Atlético Madrid | - | Athletic Club | 1:0 | |
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| 21. Ronde | 30.01.1966 | Real Madrid | - | Atlético Madrid | 3:1 | ||||
| 26. Ronde | 06.03.1966 | Atlético Madrid | - | Pontevedra CF | 4:0 | |
Honduras