| 1. Ronde | 13.08.2022 | Real Valladolid | - | Villarreal CF | 0:3 | ||||
| 2. Ronde | 19.08.2022 | Sevilla FC | - | Real Valladolid | 1:1 |  |
|||
| 3. Ronde | 28.08.2022 | FC Barcelona | - | Real Valladolid | 4:0 | ||||
| 4. Ronde | 05.09.2022 | Real Valladolid | - | UD Almería | 1:0 | ||||
| 5. Ronde | 09.09.2022 | Girona FC | - | Real Valladolid | 2:1 | ||||
| 15. Ronde | 30.12.2022 | Real Valladolid | - | Real Madrid | 0:2 | ||||
| 18. Ronde | 21.01.2023 | Atlético Madrid | - | Real Valladolid | 3:0 | ||||
| 19. Ronde | 29.01.2023 | Real Valladolid | - | Valencia CF | 1:0 | ||||
| 20. Ronde | 05.02.2023 | Real Sociedad | - | Real Valladolid | 0:1 | ||||
| 21. Ronde | 12.02.2023 | Real Valladolid | - | CA Osasuna | 0:0 | ||||
| 22. Ronde | 18.02.2023 | Real Betis | - | Real Valladolid | 2:1 | |
|||
| 23. Ronde | 26.02.2023 | Celta de Vigo | - | Real Valladolid | 3:0 | ||||
| 27. Ronde | 02.04.2023 | Real Madrid | - | Real Valladolid | 6:0 | ||||
| 29. Ronde | 15.04.2023 | Villarreal CF | - | Real Valladolid | 1:2 | ||||
| 30. Ronde | 22.04.2023 | Real Valladolid | - | Girona FC | 1:0 | ||||
| 32. Ronde | 30.04.2023 | Real Valladolid | - | Atlético Madrid | 2:5 | ||||
| 33. Ronde | 04.05.2023 | Rayo Vallecano | - | Real Valladolid | 2:1 | ||||
| 38. Ronde | 04.06.2023 | Real Valladolid | - | Getafe CF | 0:0 |
Spanje