| 3. Ronde | 27.09.2020 | Real Valladolid | - | Celta de Vigo | 1:1 | ||||
| 4. Ronde | 30.09.2020 | Real Madrid | - | Real Valladolid | 1:0 | ||||
| 6. Ronde | 18.10.2020 | SD Huesca | - | Real Valladolid | 2:2 | ||||
| 7. Ronde | 25.10.2020 | Real Valladolid | - | Deportivo Alavés | 0:2 | ||||
| 8. Ronde | 02.11.2020 | Villarreal CF | - | Real Valladolid | 2:0 |  |
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| 9. Ronde | 08.11.2020 | Real Valladolid | - | Athletic Club | 2:1 | |
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| 14. Ronde | 19.12.2020 | Sevilla FC | - | Real Valladolid | 1:1 |  |
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| 16. Ronde | 29.12.2020 | Cádiz CF | - | Real Valladolid | 0:0 |
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