| 3. Ronde | 23.09.2000 | Real Madrid | - | Athletic Club | 4:1 | ||||
| 4. Ronde | 01.10.2000 | Athletic Club | - | RCD Mallorca | 2:1 | ||||
| 5. Ronde | 15.10.2000 | CD Numancia | - | Athletic Club | 0:0 |  |
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| 7. Ronde | 28.10.2000 | Villarreal CF | - | Athletic Club | 0:0 | ||||
| 13. Ronde | 03.12.2000 | Deportivo Alavés | - | Athletic Club | 2:1 |  |
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| 14. Ronde | 10.12.2000 | Athletic Club | - | Real Oviedo | 4:0 | |
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| 15. Ronde | 17.12.2000 | Real Valladolid | - | Athletic Club | 0:0 | ||||
| 16. Ronde | 20.12.2000 | Athletic Club | - | Valencia CF | 1:1 | ||||
| 17. Ronde | 06.01.2001 | Málaga CF | - | Athletic Club | 2:1 | ||||
| 25. Ronde | 04.03.2001 | UD Las Palmas | - | Athletic Club | 0:0 | ||||
| 26. Ronde | 10.03.2001 | Athletic Club | - | Villarreal CF | 1:1 | ||||
| 27. Ronde | 18.03.2001 | Real Zaragoza | - | Athletic Club | 2:2 | ||||
| 28. Ronde | 01.04.2001 | Athletic Club | - | CA Osasuna | 0:1 | ||||
| 29. Ronde | 08.04.2001 | Celta de Vigo | - | Athletic Club | 2:1 | ||||
| 30. Ronde | 15.04.2001 | Athletic Club | - | Espanyol | 0:1 | ||||
| 31. Ronde | 22.04.2001 | Rayo Vallecano | - | Athletic Club | 1:2 | ||||
| 38. Ronde | 16.06.2001 | Racing Santander | - | Athletic Club | 3:0 |
Spanje