| 1. Ronde | 31.08.1991 | Athletic Club | - | Sevilla FC | 0:2 | ||||
| 2. Ronde | 08.09.1991 | Sporting Gijón | - | Athletic Club | 3:2 |  |
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| 3. Ronde | 14.09.1991 | Athletic Club | - | Real Madrid | 1:4 | |
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| 4. Ronde | 29.09.1991 | CD Logroñés | - | Athletic Club | 0:1 |  |
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| 5. Ronde | 06.10.1991 | Athletic Club | - | Deportivo La Coruña | 0:0 | ||||
| 7. Ronde | 27.10.1991 | Athletic Club | - | Real Burgos | 0:0 | ||||
| 8. Ronde | 03.11.1991 | RCD Mallorca | - | Athletic Club | 1:2 |  |
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| 9. Ronde | 10.11.1991 | Athletic Club | - | Espanyol | 0:2 | ||||
| 13. Ronde | 08.12.1991 | Athletic Club | - | Atlético Madrid | 3:2 | ||||
| 14. Ronde | 15.12.1991 | CA Osasuna | - | Athletic Club | 1:1 | |
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| 15. Ronde | 21.12.1991 | Athletic Club | - | Valencia CF | 2:3 | ||||
| 20. Ronde | 02.02.1992 | Sevilla FC | - | Athletic Club | 1:2 | |
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| 21. Ronde | 09.02.1992 | Athletic Club | - | Sporting Gijón | 2:0 | ||||
| 22. Ronde | 16.02.1992 | Real Madrid | - | Athletic Club | 5:0 | ||||
| 32. Ronde | 26.04.1992 | Atlético Madrid | - | Athletic Club | 3:1 |
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