| 1. Ronde | 19.08.2024 | Real Valladolid | - | Espanyol | 1:0 | ||||
| 2. Ronde | 25.08.2024 | Real Madrid | - | Real Valladolid | 3:0 | ||||
| 3. Ronde | 28.08.2024 | Real Valladolid | - | CD Leganés | 0:0 | ||||
| 4. Ronde | 31.08.2024 | FC Barcelona | - | Real Valladolid | 7:0 | ||||
| 5. Ronde | 15.09.2024 | Celta de Vigo | - | Real Valladolid | 3:1 | ||||
| 6. Ronde | 21.09.2024 | Real Valladolid | - | Real Sociedad | 0:0 | ||||
| 7. Ronde | 24.09.2024 | Sevilla FC | - | Real Valladolid | 2:1 | ||||
| 10. Ronde | 18.10.2024 | Deportivo Alavés | - | Real Valladolid | 2:3 | ||||
| 11. Ronde | 26.10.2024 | Real Valladolid | - | Villarreal CF | 1:2 | ||||
| 12. Ronde | 02.11.2024 | CA Osasuna | - | Real Valladolid | 1:0 | ||||
| 13. Ronde | 10.11.2024 | Real Valladolid | - | Athletic Club | 1:1 | ||||
| 15. Ronde | 30.11.2024 | Real Valladolid | - | Atlético Madrid | 0:5 | ||||
| 16. Ronde | 07.12.2024 | UD Las Palmas | - | Real Valladolid | 2:1 |  |
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| 17. Ronde | 13.12.2024 | Real Valladolid | - | Valencia CF | 1:0 |
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