| 6. Ronde | 10.10.1965 | Espanyol | - | Athletic Club | 3:4 | ||||
| 7. Ronde | 17.10.1965 | Athletic Club | - | Real Zaragoza | 2:0 | ||||
| 8. Ronde | 31.10.1965 | Elche CF | - | Athletic Club | 0:0 | ||||
| 9. Ronde | 14.11.1965 | Athletic Club | - | Sevilla FC | 1:0 | ||||
| 10. Ronde | 21.11.1965 | CD Málaga | - | Athletic Club | 2:0 | ||||
| 11. Ronde | 28.11.1965 | UD Las Palmas | - | Athletic Club | 1:1 | ||||
| 12. Ronde | 05.12.1965 | Athletic Club | - | Real Madrid | 2:0 | ||||
| 13. Ronde | 12.12.1965 | FC Barcelona | - | Athletic Club | 1:0 | ||||
| 17. Ronde | 06.01.1966 | Athletic Club | - | Pontevedra CF | 2:0 | ||||
| 18. Ronde | 09.01.1966 | Valencia CF | - | Athletic Club | 1:1 | ||||
| 30. Ronde | 03.04.1966 | Athletic Club | - | CE Sabadell | 3:0 |
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