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| U | Athletic Bilbao | - | FC Barcelona | 0:0 (0:0) | ||
| R | FC Barcelona | - | Athletic Bilbao | 0:1 (0:1) | ||
| U: 10.05.2023 18:00 | R: 14.05.2023 16:00 | Winnaars: Athletic Bilbao | ||||
| U | Valencia CF | - | Real Betis | 1:3 (1:2) | ||
| R | Real Betis | - | Valencia CF | 1:2 (0:2) | ||
| U: 10.05.2023 19:30 | R: 14.05.2023 19:00 | Winnaars: Real Betis | ||||
| U | Atlético Madrid | - | Real Madrid | 0:2 (0:1) | ||
| R | Real Madrid | - | Atlético Madrid | 2:2 (0:2, 0:2) n.v. | ||
| U: 10.05.2023 19:30 | R: 14.05.2023 16:00 | Winnaars: Real Madrid | ||||
| U | UD Las Palmas | - | Celta de Vigo | 5:0 (2:0) | ||
| R | Celta de Vigo | - | UD Las Palmas | 3:4 (0:2) | ||
| U: 10.05.2023 20:00 | R: 14.05.2023 11:00 | Winnaars: UD Las Palmas | ||||
