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| 09.08.2022 | 20:30 | Brora Rangers FC | - | Aberdeen FC (R) | 2:0 (0:0) | |
| 20:45 | Fraserburgh FC | - | St. Johnstone FC (R) | 0:2 (0:1) | ||
| 20:45 | Elgin City | - | Dundee United (R) | 1:0 (0:0) | ||
| 20:45 | Bonnyrigg Rose Athletic | - | Livingston FC (R) | 1:3 (0:0, 0:0) d.p. | ||
| 20:45 | St. Mirren FC (R) | - | East Stirlingshire FC | 2:4 (0:0, 0:0) d.p. | ||
| 20:45 | Motherwell FC (R) | - | East Kilbride FC | 1:2 (0:1) | ||
| 20:45 | Albion Rovers | - | Celtic FC (R) | 2:3 (2:2) | ||
| 20:45 | Kilmarnock FC (R) | - | Cowdenbeath FC | 3:0 (2:0) | ||
| 10.08.2022 | 20:45 | Hibernian FC (R) | - | Brechin City FC | 1:4 (0:0, 1:1) d.p. | |
| 20:45 | The Spartans FC | - | Rangers FC (R) | 0:1 (0:0) | ||
| 21:00 | Heart of Midlothian (R) | - | Buckie Thistle | 2:3 (1:0) |
