| 3. Ronde | 29.08.2022 | Cádiz CF | - | Athletic Club | 0:4 | ||||
| 6. Ronde | 17.09.2022 | Athletic Club | - | Rayo Vallecano | 3:2 | ||||
| 7. Ronde | 30.09.2022 | Athletic Club | - | UD Almería | 4:0 | ||||
| 17. Ronde | 14.01.2023 | Real Sociedad | - | Athletic Club | 3:1 | ||||
| 18. Ronde | 22.01.2023 | Athletic Club | - | Real Madrid | 0:2 | ||||
| 21. Ronde | 11.02.2023 | Valencia CF | - | Athletic Club | 1:2 | ||||
| 22. Ronde | 19.02.2023 | Atlético Madrid | - | Athletic Club | 1:0 | ||||
| 23. Ronde | 26.02.2023 | Athletic Club | - | Girona FC | 2:3 |  |
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| 28. Ronde | 08.04.2023 | Espanyol | - | Athletic Club | 1:2 | ||||
| 32. Ronde | 01.05.2023 | RCD Mallorca | - | Athletic Club | 1:1 | ||||
| 33. Ronde | 04.05.2023 | Athletic Club | - | Real Betis | 0:1 | ||||
| 34. Ronde | 13.05.2023 | Villarreal CF | - | Athletic Club | 5:1 | |
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| 35. Ronde | 20.05.2023 | Athletic Club | - | Celta de Vigo | 2:1 | |
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| 36. Ronde | 25.05.2023 | CA Osasuna | - | Athletic Club | 2:0 | ||||
| 37. Ronde | 28.05.2023 | Athletic Club | - | Elche CF | 0:1 | ||||
| 38. Ronde | 04.06.2023 | Real Madrid | - | Athletic Club | 1:1 |
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