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| 16.09.2022 | 21:00 | Real Valladolid | - | Cádiz CF | 0:1 (0:0) | |
| 17.09.2022 | 14:00 | RCD Mallorca | - | UD Almería | 1:0 (1:0) | |
| 16:15 | FC Barcelona | - | Elche CF | 3:0 (2:0) | ||
| 18:30 | Valencia CF | - | Celta de Vigo | 3:0 (1:0) | ||
| 21:00 | Athletic Bilbao | - | Rayo Vallecano | 3:2 (3:1) | ||
| 18.09.2022 | 14:00 | CA Osasuna | - | Getafe CF | 0:2 (0:1) | |
| 16:15 | Villarreal CF | - | Sevilla FC | 1:1 (0:1) | ||
| 18:30 | Real Betis | - | Girona FC | 2:1 (1:1) | ||
| 18:30 | Real Sociedad | - | Espanyol | 2:1 (2:1) | ||
| 21:00 | Atlético Madrid | - | Real Madrid | 1:2 (0:2) |
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Real Madrid | 6 | 6 | 0 | 0 | 17:6 | 11 | 18 |
| 2 |
|
FC Barcelona | 6 | 5 | 1 | 0 | 18:1 | 17 | 16 |
| 3 |
|
Real Betis | 6 | 5 | 0 | 1 | 10:4 | 6 | 15 |
| 4 |
|
Athletic Bilbao | 6 | 4 | 1 | 1 | 12:4 | 8 | 13 |
| 5 |
|
CA Osasuna | 6 | 4 | 0 | 2 | 7:5 | 2 | 12 |
| 6 |
|
Villarreal CF | 6 | 3 | 2 | 1 | 10:2 | 8 | 11 |
| 7 |
|
Atlético Madrid | 6 | 3 | 1 | 2 | 10:6 | 4 | 10 |
| 8 |
|
Real Sociedad | 6 | 3 | 1 | 2 | 7:8 | -1 | 10 |
| 9 |
|
Valencia CF | 6 | 3 | 0 | 3 | 10:5 | 5 | 9 |
| 10 |
|
RCD Mallorca | 6 | 2 | 2 | 2 | 6:7 | -1 | 8 |
| 11 |
|
Girona FC | 6 | 2 | 1 | 3 | 7:7 | 0 | 7 |
| 12 |
|
Rayo Vallecano | 6 | 2 | 1 | 3 | 7:8 | -1 | 7 |
| 13 |
|
Getafe CF | 6 | 2 | 1 | 3 | 6:12 | -6 | 7 |
| 14 |
|
Celta de Vigo | 6 | 2 | 1 | 3 | 8:13 | -5 | 7 |
| 15 |
|
Sevilla FC | 6 | 1 | 2 | 3 | 7:11 | -4 | 5 |
| 16 |
|
Espanyol | 6 | 1 | 1 | 4 | 7:12 | -5 | 4 |
| 17 |
|
Real Valladolid | 6 | 1 | 1 | 4 | 3:11 | -8 | 4 |
| 18 |
|
UD Almería | 6 | 1 | 1 | 4 | 4:7 | -3 | 4 |
| 19 |
|
Cádiz CF | 6 | 1 | 0 | 5 | 1:14 | -13 | 3 |
| 20 |
|
Elche CF | 6 | 0 | 1 | 5 | 2:16 | -14 | 1 |
| Champions League | |
| Europa League | |
| Degradatie |
