| 1. Ronde | 27.08.2006 | Athletic Club | - | Real Sociedad | 1:1 | ||||
| 3. Ronde | 17.09.2006 | Athletic Club | - | Atlético Madrid | 1:4 | ||||
| 4. Ronde | 24.09.2006 | Getafe CF | - | Athletic Club | 0:0 | ||||
| 5. Ronde | 30.09.2006 | Athletic Club | - | FC Barcelona | 1:3 | ||||
| 6. Ronde | 15.10.2006 | Gimnàstic de Tarragona | - | Athletic Club | 2:3 | ||||
| 12. Ronde | 26.11.2006 | Athletic Club | - | Sevilla FC | 1:3 | ||||
| 14. Ronde | 10.12.2006 | Athletic Club | - | Recreativo Huelva | 4:2 |  |
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| 15. Ronde | 16.12.2006 | Deportivo La Coruña | - | Athletic Club | 0:2 | ||||
| 16. Ronde | 19.12.2006 | Athletic Club | - | Real Zaragoza | 0:0 | ||||
| 17. Ronde | 07.01.2007 | RCD Mallorca | - | Athletic Club | 1:3 | ||||
| 19. Ronde | 21.01.2007 | Levante UD | - | Athletic Club | 0:0 | ||||
| 20. Ronde | 28.01.2007 | Real Sociedad | - | Athletic Club | 0:2 | ||||
| 27. Ronde | 17.03.2007 | Athletic Club | - | CA Osasuna | 0:3 | ||||
| 28. Ronde | 01.04.2007 | Racing Santander | - | Athletic Club | 5:4 | ||||
| 29. Ronde | 07.04.2007 | Athletic Club | - | Valencia CF | 1:0 | ||||
| 30. Ronde | 15.04.2007 | Athletic Club | - | Espanyol | 2:1 |
Spanje