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| 23.09.2006 | 22:00 | Real Betis | - | Real Madrid | 0:1 (0:1) | |
| 24.09.2006 | 19:00 | Atlético Madrid | - | Sevilla FC | 2:1 (0:1) | |
| 20:00 | RCD Mallorca | - | Espanyol | 1:0 (0:0) | ||
| 20:00 | Villarreal CF | - | Real Zaragoza | 3:2 (0:1) | ||
| 20:00 | Levante UD | - | Deportivo La Coruña | 2:0 (1:0) | ||
| 20:00 | Real Sociedad | - | Recreativo Huelva | 2:3 (0:1) | ||
| 20:00 | Getafe CF | - | Athletic Bilbao | 0:0 (0:0) | ||
| 20:00 | Gimnàstic de Tarragona | - | Racing Santander | 2:2 (1:0) | ||
| 20:00 | Celta de Vigo | - | CA Osasuna | 0:2 (0:1) | ||
| 21:00 | FC Barcelona | - | Valencia CF | 1:1 (0:1) |
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Valencia CF | 4 | 3 | 1 | 0 | 6:2 | 4 | 10 |
| 2 |
|
Real Madrid | 4 | 3 | 1 | 0 | 7:1 | 6 | 10 |
| 3 |
|
FC Barcelona | 4 | 3 | 1 | 0 | 10:3 | 7 | 10 |
| 4 |
|
Sevilla FC | 4 | 3 | 0 | 1 | 11:5 | 6 | 9 |
| 5 |
|
Atlético Madrid | 4 | 3 | 0 | 1 | 7:3 | 4 | 9 |
| 6 |
|
Deportivo La Coruña | 4 | 2 | 1 | 1 | 5:4 | 1 | 7 |
|
Recreativo Huelva | 4 | 2 | 1 | 1 | 5:4 | 1 | 7 | |
| 8 |
|
Getafe CF | 4 | 2 | 1 | 1 | 3:2 | 1 | 7 |
| 9 |
|
Real Zaragoza | 4 | 2 | 0 | 2 | 9:6 | 3 | 6 |
| 10 |
|
CA Osasuna | 4 | 2 | 0 | 2 | 4:5 | -1 | 6 |
| 11 |
|
Levante UD | 4 | 2 | 0 | 2 | 4:8 | -4 | 6 |
| 12 |
|
RCD Mallorca | 4 | 1 | 2 | 1 | 2:3 | -1 | 5 |
| 13 |
|
Gimnàstic de Tarragona | 4 | 1 | 1 | 2 | 4:6 | -2 | 4 |
| 14 |
|
Villarreal CF | 4 | 1 | 1 | 2 | 3:5 | -2 | 4 |
| 15 |
|
Real Betis | 4 | 1 | 0 | 3 | 6:6 | 0 | 3 |
| 16 |
|
Celta de Vigo | 4 | 1 | 0 | 3 | 5:8 | -3 | 3 |
| 17 |
|
Espanyol | 4 | 1 | 0 | 3 | 2:6 | -4 | 3 |
| 18 |
|
Athletic Bilbao | 4 | 0 | 2 | 2 | 2:8 | -6 | 2 |
| 19 |
|
Real Sociedad | 4 | 0 | 1 | 3 | 4:9 | -5 | 1 |
| 20 |
|
Racing Santander | 4 | 0 | 1 | 3 | 2:7 | -5 | 1 |
