| 1. Ronde | 13.09.2020 | Villarreal CF | - | SD Huesca | 1:1 | ||||
| 2. Ronde | 19.09.2020 | Villarreal CF | - | SD Eibar | 2:1 | ||||
| 3. Ronde | 27.09.2020 | FC Barcelona | - | Villarreal CF | 4:0 | ||||
| 4. Ronde | 30.09.2020 | Villarreal CF | - | Deportivo Alavés | 3:1 | ||||
| 5. Ronde | 03.10.2020 | Atlético Madrid | - | Villarreal CF | 0:0 |  |
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| 6. Ronde | 18.10.2020 | Villarreal CF | - | Valencia CF | 2:1 | |
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| 7. Ronde | 25.10.2020 | Cádiz CF | - | Villarreal CF | 0:0 | ||||
| 8. Ronde | 02.11.2020 | Villarreal CF | - | Real Valladolid | 2:0 | ||||
| 9. Ronde | 08.11.2020 | Getafe CF | - | Villarreal CF | 1:3 | |
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| 10. Ronde | 21.11.2020 | Villarreal CF | - | Real Madrid | 1:1 | ||||
| 11. Ronde | 29.11.2020 | Real Sociedad | - | Villarreal CF | 1:1 | |
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| 12. Ronde | 06.12.2020 | Villarreal CF | - | Elche CF | 0:0 | ||||
| 13. Ronde | 13.12.2020 | Real Betis | - | Villarreal CF | 1:1 |
Spanje
