| 3. Ronde | 12.09.2021 | FC Barcelona B | - | UE Costa Brava | 0:0 | ||||
| 8. Ronde | 16.10.2021 | Real Madrid Castilla | - | FC Barcelona B | 0:0 | ||||
| 9. Ronde | 23.10.2021 | FC Barcelona B | - | CD Alcoyano | 0:0 |  |
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| 11. Ronde | 06.11.2021 | FC Barcelona B | - | Sevilla Atlético | 4:0 | ||||
| 13. Ronde | 21.11.2021 | Albacete | - | FC Barcelona B | 2:0 | ||||
| 14. Ronde | 27.11.2021 | FC Barcelona B | - | San Fernando CD | 0:2 | ||||
| 18. Ronde | 09.01.2022 | FC Barcelona B | - | Real Betis B | 1:2 | |
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| 19. Ronde | 22.01.2022 | FC Barcelona B | - | UCAM Murcia CF | 2:2 | ||||
| 20. Ronde | 25.01.2022 | UE Costa Brava | - | FC Barcelona B | 2:2 | ||||
| 21. Ronde | 29.01.2022 | FC Barcelona B | - | Real Madrid Castilla | 2:2 |  |
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| 22. Ronde | 05.02.2022 | Algeciras CF | - | FC Barcelona B | 2:1 | ||||
| 30. Ronde | 03.04.2022 | RB Linense | - | FC Barcelona B | 1:2 | ||||
| 33. Ronde | 23.04.2022 | FC Barcelona B | - | Atlético Sanluqueño CF | 5:0 | ||||
| 34. Ronde | 30.04.2022 | San Fernando CD | - | FC Barcelona B | 0:2 | ||||
| 35. Ronde | 07.05.2022 | FC Barcelona B | - | CE Sabadell | 0:2 | ||||
| 37. Ronde | 21.05.2022 | FC Barcelona B | - | CD Castellón | 5:0 | ||||
| 38. Ronde | 28.05.2022 | UCAM Murcia CF | - | FC Barcelona B | 1:2 |
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