| 4. Ronde | 22.09.2010 | Real Zaragoza | - | Hércules CF | 0:0 | ||||
| 5. Ronde | 26.09.2010 | Hércules CF | - | Sevilla FC | 2:0 | ||||
| 7. Ronde | 18.10.2010 | Hércules CF | - | Villarreal CF | 2:2 | ||||
| 8. Ronde | 24.10.2010 | UD Almería | - | Hércules CF | 1:1 | ||||
| 9. Ronde | 30.10.2010 | Hércules CF | - | Real Madrid | 1:3 | ||||
| 16. Ronde | 20.12.2010 | Racing Santander | - | Hércules CF | 0:0 | ||||
| 18. Ronde | 10.01.2011 | Hércules CF | - | Atlético Madrid | 4:1 | ||||
| 20. Ronde | 24.01.2011 | Athletic Club | - | Hércules CF | 3:0 |  |
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| 22. Ronde | 06.02.2011 | Valencia CF | - | Hércules CF | 2:0 | ||||
| 30. Ronde | 03.04.2011 | Real Sociedad | - | Hércules CF | 1:3 | ||||
| 33. Ronde | 24.04.2011 | Hércules CF | - | Deportivo La Coruña | 1:0 | ||||
| 34. Ronde | 01.05.2011 | Málaga CF | - | Hércules CF | 3:1 | ||||
| 35. Ronde | 07.05.2011 | Hércules CF | - | Racing Santander | 2:3 | ||||
| 38. Ronde | 21.05.2011 | Hércules CF | - | Sporting Gijón | 0:0 |
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