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| U | Fluminense RJ | - | Athletico Paranaense | 2:4 (1:2) | ||
| R | Athletico Paranaense | - | Fluminense RJ | 3:2 (1:0) | ||
| U: 12.10.2022 16:00 | R: 18.10.2022 20:30 | Winnaars: Athletico Paranaense | ||||
| U | Palmeiras | - | Atlético Mineiro | 4:2 (0:1) | ||
| R | Atlético Mineiro | - | Palmeiras | 3:2 (1:1) | ||
| U: 12.10.2022 21:00 | R: 20.10.2022 20:45 | Winnaars: Palmeiras | ||||
| U | Fortaleza | - | Santos FC | 0:2 (0:0) | ||
| R | Santos FC | - | Fortaleza | 4:0 (2:0) | ||
| U: 13.10.2022 20:00 | R: 19.10.2022 20:00 | Winnaars: Santos FC | ||||
| U | Grêmio Porto Alegre | - | Vasco da Gama | 2:0 (1:0) | ||
| R | Vasco da Gama | - | Grêmio Porto Alegre | 1:2 (0:0) | ||
| U: 13.10.2022 20:00 | R: 21.10.2022 20:45 | Winnaars: Grêmio Porto Alegre | ||||
