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| U | Corinthians SP | - | Flamengo RJ | 0:2 (0:1) | ||
| R | Flamengo RJ | - | Corinthians SP | 1:0 (0:0) | ||
| U: 03.08.2022 02:30 | R: 10.08.2022 02:30 | Winnaars: Flamengo RJ | ||||
| U | Vélez Sarsfield | - | Talleres de Córdoba | 3:2 (1:0) | ||
| R | Talleres de Córdoba | - | Vélez Sarsfield | 0:1 (0:0) | ||
| U: 04.08.2022 02:30 | R: 11.08.2022 02:30 | Winnaars: Vélez Sarsfield | ||||
| U | Atlético Mineiro | - | Palmeiras | 2:2 (1:0) | ||
| R | Palmeiras | - | Atlético Mineiro | 6:5 (0:0, 0:0) d.p. | ||
| U: 04.08.2022 02:30 | R: 11.08.2022 02:30 | Winnaars: Palmeiras | ||||
| U | Athletico Paranaense | - | Estudiantes | 0:0 (0:0) | ||
| R | Estudiantes | - | Athletico Paranaense | 0:1 (0:0) | ||
| U: 05.08.2022 02:30 | R: 12.08.2022 02:30 | Winnaars: Athletico Paranaense | ||||
